|
週次 |
日期 |
單元主題 |
|
第1週 |
09/18 |
Lecture 1: Basic Electrochemistry Review
1.1. Electrochemical potential and thermodynamics
(a) Simple Nernst equation (2.1.3, 2.1.5, 2.1.6) vs. the binary solution model for insertion electrochemistry (paper)
(b) Electrochemical potential equilibrium and applications to liquid junction and selective membrane (2.2.4, 2.2.5, 2.3, 2.4)
1.2. Electrochemical current and reaction kinetics
(a) Electrode kinetics (3.2, 3.3)
(b) Implications of the Bulter-Volmer model for the one-step, one-electron process (3.4)
(c) Applications to GOR (paper) |
|
第2週 |
09/25 |
Lecture 2: Diffusion-Controlled Currents
2.1. Basics of mass Transfer (4.1, 4.2, 4.4)
2.2. Potential step under diffusion control (5.2, 5.8)
2.3. Diffusion-controlled currents at ultramicroelectrodes (5.3, 5.9)
2.4. General theory of controlled current methods (8.2)
2.5. Diffusivity determination and non-linear diffusion behaviors (paper) |
|
第3週 |
10/02 |
No class (mid-autumn festival) |
|
第4週 |
10/09 |
No class (national day) |
|
第5週 |
10/16 |
Lecture 3: Voltammetry for Reversible Systems
3.1. Sampled-current voltammetry (5.4.1, 5.4.2)
3.2. Voltammetry for Nernstian systems (6.2)
3.3. Convolutive or semi-integral techniques (6.7)
3.4. Polargraphy (7.1.2)
3.5. Pulse voltammetry (7.3) |
|
第6週 |
10/23 |
Lecture 4: Methods Involving Forced Convection
4.1. Theoretical treatment of convective systems (9.2)
4.2. Rotating disk electrode (9.3)
4.3. Convection at UMEs (9.7)
4.4. Electrodynamics and related phenomena (9.8) |
|
第7週 |
10/30 |
Lecture 5: Electrochemical Impedance Spectroscopy
5.1. AC electrochemistry (10.1)
5.2. Faradaic impedance (10.2)
5.3. Kinetic parameterization (10.3)
5.4. Electrochemical impedance spectroscopy (10.4)
5.5. AC voltammetry (10.5) |
|
第8週 |
11/06 |
Lecture 6: Bulk Electrolysis Methods
6.1. Flow electrolysis (11.6)
6.2. Thin-layer electrochemistry (11.7)
6.3. Stripping analysis (11.8) |
|
第9週 |
11/13 |
Lecture 7: Electrode Reactions with Coupled Homogeneous Chemical Reactions
7.1 Classification of reactions (12.1)
7.2 Theory for transient voltammetry (12.3) |
|
第10週 |
11/20 |
Lecture 8: Double-Layer Structure
8.1. Thermodynamics of the double layer (13.1)
8.2. Experimental evaluation of surface excess (13.2)
8.3. Models for double-layer structure (13.3) |
|
第11週 |
11/27 |
Lecture 9: Studies at Solid Electrodes
9.1. Solid electrodes (13.4)
9.2. Specific adsorption (13.5)
9.3. Effect of adsorption of electroinactive species (13.6)
9.4. Double-layer effects on electrode reaction rates (13.7) |
|
第12週 |
12/04 |
Lecture 10: Chemically Modified Electrodes (I)
10.1. Types, preparation, and properties of films and modified electrodes (14.1, 14.2)
10.2. Electrochemical responses of adsorbed monolayers (14.3) |
|
第13週 |
12/11 |
Lecture 11: Chemically Modified Electrodes (II)
11.1. Overview of processes at modified electrodes (14.4)
11.2. Blocking layers (14.5)
11.3. Other methods of characterization (14.6) |
|
第14週 |
12/18 |
Lecture 12: Scanning Probe Techniques
12.1. Scanning tunneling microscopy (16.2)
12.2. Atomic force microscopy (16.3)
12.3. Scanning electrochemical microscopy (16.4) |
|
第15週 |
12/25 |
Lecture 13: Spectroelectrochemistry
13.1. Ultraviolet and visible spectroscopy (17.1)
13.2. Vibrational spectroscopy (17.2) |
|
第16週 |
2021/01/01 |
No class (new year) |
|
第17週 |
2021/01/08 |
Lecture 14: Other Coupled Characterization Methods
14.1. Electron and ion spectrometry (17.3)
14.2. Magnetic resonance methods (17.4)
14.3. Quartz crystal microbalance (17.5)
14.4. X-ray methods (17.6) |
|
第18週 |
2021/01/15 |
Lecture 15: Photoelectrochemistry at Semiconductor Electrodes
15.1. Band theory (3.6)
15.2. Semiconductor electrodes (18.2.2)
15.3. Current-potential curves at semiconductor electrodes (18.2.3)
15.4. Photoeffects at semiconductor electrodes (18.2.4)
15.5. Surface photocatalytic processes at semiconductor particles (18.2.5) |